| 000 | 02380nam a2200277Ia 4500 | ||
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| 003 | UNASAM BIBLIOTECA CENTRAL | ||
| 005 | 20220824115656.0 | ||
| 008 | 210122b ###||||| |||| 00| 0 spa d | ||
| 020 | _a9783658087951 | ||
| 040 |
_aUNASAM BIBLIOTECA CENTRAL _cUNASAM BIBLIOTECA CENTRAL |
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| 041 | _aeng | ||
| 043 | _cDEU | ||
| 082 |
_a541.2242 _bH42 _222a ed. |
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| 100 |
_aHerrmann, Sven _eautor |
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| 245 | 0 |
_aNew Synthetic Routes to Poloyoxometalate Containing Ionic Liquids : _b An Investigation of Their Properties / _c Sven Herrmann |
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| 260 |
_aWiesbaden _bSpringer, _c2015 |
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| 300 |
_axxi, 122 p. : _bils. ; _c25 cm. |
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| 490 | _a BestMasters | ||
| 520 | _aIn his Master project Sven Herrmann for the first time carried out fundamental investigations into the development of polyoxometalate based ionic liquids (POM-ILs). The POM-ILs were obtained by charge balancing inorganic polyoxometalate (POM) anions with sterically demanding tetraalkylammonium or tetraalkylphosphonium cations. By functionalization of lacunary Keggin clusters with 3d-transition metals and charge balancing with tetraalkylammonium cations of differing chain length, a model system for the correlation of the molecular structure with macroscopic materials properties was obtained. In a systematic approach the syntheses via self-aggregation is presented. Analytic methods comprise UV-Vis, FTIR, NMR, EPR and M©œ©ℓbauer spectroscopy. For determination of the materials properties TGA and DSC were carried out and rheological studies shed light onto the flow characteristics of the highly viscous materials. ℗ℓContents Polyoxometlates and Ionic Liquids in General POM-Ils as New Class of Compounds Synthesis and Characterization of POM-ILs Reactivity Towards Azide and Carbonmonoxide ℗ℓTarget Groups Researchers and students in the field of chemistry Practitioners in this area ℗ℓThe Author Sven Herrmann obtained his Masters degree at the University of Erlangen-N©ơrnberg. He then joined the working group of Prof. Carsten Streb in the inorganic department at the University of Ulm to work on his PhD thesis that targets the development of polyoxometalate based ionic liquids (POM-ILs). | ||
| 650 | _aINGENIERIA QUIMICA | ||
| 650 | _aQUIMICA | ||
| 650 | _aQUIMICA INORGANICA | ||
| 700 | _a Juaneda Ortolá, Francisco José | ||
| 942 |
_cLIBRO _2ddc |
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| 999 |
_c28945 _d28945 |
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